Abstract: Objective To study the chemical constituents of Smilax china.Methods The compounds were isolated by silica gel,Sephadex LH-20,ODS chromatography,and semi-preparative HPLC.Their structures were elucidated on the basis of MS and NMR spectroscopic analyses.Results Seven flavonoids and four stilbenes were isolated and identified as dihydrokaempferol-5-O-β-D-glucoside(Ⅰ),engeletin (Ⅱ),isoengeletin (Ⅲ),dihydroquercetin-3-O-glycoside(Ⅳ),3,5,7,3',5'-pentahydroxy-flavanonol (Ⅴ),astilbin (Ⅵ),quercetin-3'-O-glycoside(Ⅶ),piceid(Ⅷ),scirpusin A (Ⅸ),resveratrol (Ⅹ),and oxyresveratrol (Ⅺ).Conclusion Compounds Ⅳ-Ⅸ are isolated from this plant for the first time,among which the ~(13)C-NMR data of compound Ⅸ is reported firstly.